题目：

Ion–Dipole Interaction Enabling Highly Efficient CsPbI3 Perovskite Indoor Photovoltaics

作者：

Kai-Li Wang, Haizhou Lu, Meng Li, Chun-Hao Chen, Ding- Bo Zhang, Jing Chen, Jun-Jie Wu, Yu-Hang Zhou, Xue-Qi Wang, Zhen-Huang Su, Yi-Ran Shi, Qi-Sheng Tian, Yu-Xiang Ni, Xing-Yu Gao, Shaik M. Zakeeruddin, Michael Grätzel*, Zhao-Kui Wang*, Liang-Sheng Liao

摘要：

Metal halide perovskites are ideal candidates for indoor photovoltaics (IPVs) because of their easy-to-adjust bandgaps, which can be designed to cover the spectrum of any artificial light source. However, the serious non-radiative carrier recombination under low light illumination restrains the application of perovskite-based IPVs (PIPVs). Herein, polar molecules of amino naphthalene sulfonates are employed to functionalize the TiO2 substrate, anchoring the CsPbI3 perovskite crystal grains with a strong ion–dipole interaction between the molecule-level polar interlayer and the ionic perovskite film. The resulting high-quality CsPbI3 films with the merit of defect-immunity and large shunt resistance under low light conditions enable the corresponding PIPVs with an indoor power conversion efficiency of up to 41.2% (Pin: 334.11 µW cm−2, Pout: 137.66 µW cm−2) under illumination from a commonly used indoor light-emitting diode light source (2956 K, 1062 lux). Furthermore, the device also achieves efficiencies of 29.45% (Pout: 9.80 µW cm−2) and 32.54% (Pout: 54.34 µW cm−2) at 106 (Pin: 33.84 µW cm−2) and 522 lux (Pin: 168.21 µW cm−2), respectively.

影响因子：

30.849

分区情况：

一区