Materials Horizons |多重共振型热活化延迟荧光发光材料系统中光谱展宽和浓度淬灭原因的分辨研究
时间: 2023-04-19 作者: 浏览次数: 778

题目:

Distinguishing the Respective Determining Factors for Spectral Broadening and Concentration Quenching in Multiple Resonance Typed TADF Emitter Systems

作者:

Feng Huang, Xiao-Chun Fan, Ying-Chun Cheng, Hao Wu,  Yi-Zhong Shi, Jia Yu, Kai Wang, Chun-Sing Lee* and Xiao-Hong Zhang*

摘要:

Multiple resonance (MR) type thermally activated delayed fluorescence (TADF) emitters have attracted much recent attention due to their narrow emission spectra and high photoluminescence quantum yields (PLQYs). Spectral broadening and concentration quenching at high doping concentrations are two issues currently limiting the development of MR-TADF emitters. However, the origins of these have not been fully clarified so far. In this work, by investigating emitters with the same MR cores but peripheral groups of different steric types, we distinguished that the spectral broadening and concentration quenching are mainly caused by excimer formation and triplet exciton annihilation, respectively. This understanding on aggregated behaviors of MR emitters provides new insight for the further development of high-performance MR-TADF emitters with low concentration sensitivities.

影响因子:

13.266

分区情况:

一区